Preheat the oven to 350°F. Spray a 9×13-inch baking pan with non-stick spray.
Place the melted unsalted butter, granulated sugar, and brown sugar in the bowl of an electric mixer. Beat on medium speed for about 3 minutes, until the mixture is slightly lightened in color.
Add the instant espresso powder and vanilla extract to the mixer and mix until combined.
Add the eggs one at a time, mixing after each addition until each egg is fully incorporated.
In a separate bowl, whisk together the all-purpose flour, unsweetened cocoa powder, and kosher salt until evenly combined.
With the mixer on low speed, add the dry ingredients to the wet ingredients and mix just until no streaks of flour remain. Do not overmix.
Fold in the semisweet chocolate chips by hand until evenly distributed.
Pour the batter into the prepared 9×13 pan and spread it into an even layer.
Bake on the center oven rack for 30 minutes. The brownies should have set edges and a slightly fudgy center; a toothpick inserted near the center will come out with a few moist crumbs.
Remove the pan from the oven and allow the brownies to cool in the pan on a wire rack before cutting and serving.